InChI=1S/C7H6N2O4/c1-5-2-3-6(8(10)11)4-7(5)9(12)13/h2-4H,1H3, InChI=1/C7H6N2O4/c1-5-2-3-6(8(10)11)4-7(5)9(12)13/h2-4H,1H3, Except where otherwise noted, data are given for materials in their, Pella, PA. J. Chem. A dinitrotoluene in which the methyl group is ortho to one of the nitro groups and para to the other. 121-14-2) and 2,6-dinitrotoluene (CAS No. Substance Details CAS Registry Number: 121-14-2 CA Index Name: Benzene, 1-methyl-2,4-dinitro *Please select more than one item to compare Most DNT is used in the production of toluene diisocyanate, which is used to produce flexible polyurethane foams. The Global 2,4-Dinitrotoluene (CAS 121-14-2) Industry 2020 Market Research Report is a professional and in-depth study on the current state of the 2,4-Dinitrotoluene industry. Linear Formula CH 3 C 6 H 3 (NO 2) 2. 2,4-dinitrotoluene Regulatory process names 11 Translated names 23 CAS names 1 IUPAC names 5 Other names 1 Other identifiers 2 Print infocard Open Substance Regulatory Obligations Most of the toxicity data are for the 2,4-DNT and 2,6-DNT isomers. Chromatogr., 71, 1972, 23-37. umn class: Semi-standard non-polar; Column diameter: 0.25 mm; Column length: 30 m; Column type: Capillary; Start T: 140 C; CAS no: 121142; Active phase: DB-5; Phase thickness: 0.25 um; Data type: Kovats RI; Authors: Hobbs, J.R.; Conde, E.P., Gas chromatographic retention indices of explosives and nitro-compounds, in Advances in Analysis and Detection of Explosives: Proceedings of the 4th International Symposium on Analysis of Detection of Explosives, September 7-10, 1992, Jerusalem Israel, J. Yinon, ed(s), Kluwer Academic Publishers, Netherlands, 1992, 153-164. ass: Semi-standard non-polar; Column diameter: 0.25 mm; Column length: 30 m; Column type: Capillary; Heat rate: 10 K/min; Start T: 40 C; End T: 310 C; Start time: 1 min; CAS no: 121142; Active phase: DB-5MS; Phase thickness: 0.5 um; Data type: Lee RI; Authors: Chen, P.H. CopyCopied, RMBFBMJGBANMMK-UHFFFAOYSA-N Molecular structure The molecular structure is based on structures generated from information available in ECHA’s databases. Chromatogr., 393, 1987, 175-194. ass: Semi-standard non-polar; Column type: Capillary; CAS no: 121142; Active phase: DB-5; Carrier gas: He; Data type: Normal alkane RI; Authors: Staples, E.J., Analysis of odors from explosives using an electronic nose, 2004. ass: Semi-standard non-polar; Column diameter: 0.25 mm; Column length: 30 m; Column type: Capillary; Heat rate: 1 K/min; Start T: 40 C; End T: 160 C; CAS no: 121142; Active phase: BPX-5; Carrier gas: H2; Phase thickness: 0.25 um; Data type: Normal alkane RI; Authors: Marriott, P.J. Dinitrotoluene; DNT; 1-methyl-2,4-dinitro benzene . DNT alone, would not be a reliable or effective explosive. : 63348-71-0 Formula: C7H5N2NaO7S Molecular Weight: 284.17900 Synonyms: 3-Methyl-2,6-dinitrobenzenesulfonic acid; 2,4 … Component of the 2,4-dinitrotoluene dioxygenase (DNTDO) multicomponent enzyme system which catalyzes the incorporation of both atoms of molecular oxygen into 2,4-dinitrotoluene (DNT) to form 4-methyl-5-nitrocatechol (MNC) and nitrite. 2,4-Dinitrotoluene Synonyms 1-Methyl-2,4-Dinitrobenzene; 2,4-Dinitrotoluol; 2,4-DNT Molecular Structure Molecular Formula C 7 H 6 N 2 O 4 Molecular Weight 182.13 CAS Registry Number 121-14-2 … The Global 2,4-Dinitrotoluene (CAS 121-14-2) Industry 2020 Market Research Report is a professional and in-depth study on the current state of the 2,4-Dinitrotoluene industry. This pale yellow crystalline solid is well known as a precursor to trinitrotoluene (TNT) but is mainly produced as a precursor to toluene diisocyanate. Degradation of 2,4-dinitrotoluene by the lignin-degrading fungus Phanerochaete chrysosporium. By continuing on our website, you accept the use of cookies. Articles of 2,4-Dinitrotoluene are included as well. Sigma-Aldrich offers a number of 2,4-Dinitrotoluene products. Chronic Product Number: D0856 * Items available from stock in Japan will be delivered in 10 business days. Chromatogr., 23(3), 2000, 253-258. class: Semi-standard non-polar; Column diameter: 0.53 mm; Column length: 30 m; Column type: Capillary; Description: 1 min at 120 0C; 120 - 200 0C at 3 deg/min; 200 0C for 2 min; 200 - 250 0C at 8 deg/min; 250 0C for 4 min; CAS no: 121142; Active phase: DB-5; Carrier gas: He; Phase thickness: 1.5 um; Data type: Normal alkane RI; Authors: Lopez-Avila, V.; Benedicto, J.; Baldin, E.; Beckert, W.F., Analysis of classes of compound of environmental concern: I. Nitroaromatic compounds, J. Hi. ; Gurka, D.F., Application of gas chromatographic retention properties to the identification of environmental contaminants, J. Table of Contents Chapter One 2,4-Dinitrotoluene Overview 1.1 2,4-Dinitrotoluene Outline 1.2 Classification and Application 1.3 Manufacturing Technology Chapter Two Industry Chain Analysis 2.1 Value Chain Analysis 2 606-20-2) have been associated, either as precursors or by products, with the synthesis of polyurethane foams, coatings, elastomers and explosives. Thermodyn. ; Jeter, J.L. Organic Compound; Industrial Precursor/Intermediate; Plasticizer; Aromatic Hydrocarbon; Explosive Agent; Nitrite; Pollutant; Industrial/Workplace Toxin; Synthetic Compound, DANGER: POISON, irritates skin, eyes, lungs. Basis for Listing: AB-US EPA. Other names: Toluene, 2,4-dinitro-; 2,4-Dinitrotoluene; 2,4-DNT; 1-Methyl-2,4-Dinitrobenzene; 2,4-Dinitrotoluol; NCI-C01865; Rcra waste number U105; Dinitrotoluol; 6-Methyl-1,3-dinitrobenzene; 4-Methyl-1,3-dinitrobenzene; NSC 7194 J., 5(4), 2005, 622-631. ass: Standard non-polar; Column type: Packed; Heat rate: 6 K/min; Start T: 70 C; End T: 220 C; CAS no: 121142; Active phase: OV-101; Data type: Kovats RI; Authors: Alley, B.J. No information is available on the acute (short-term) effects of 2,4-dinitrotoluene in humans. *Please select more than one item to compare Stable. Author information: (1)Department of Chemical and Biological Sciences, Oregon Graduate Institute of Science and Technology, Beaverton 97006-1999. CopyCopied, CSID:8150, http://www.chemspider.com/Chemical-Structure.8150.html (accessed 17:35, Dec 12, 2020) Valli K(1), Brock BJ, Joshi DK, Gold MH. Compound 2,4-Dinitrotoluenewith free spectra: 6 NMR, 6 FTIR, 1 Raman, and 14 MS. Additional Academic Resources Offers every student and faculty member unlimited access to millions of spectra and advanced software View information & documentation regarding 2,4-Dinitrotoluene, including CAS, MSDS & more. GC Mass Spectrum. Search results for 1467804 at Sigma-Aldrich Compare Products: Select up to 4 products. Molecular Weight 182.13 . It is the most common isomer of dinitrotoluene. 2,4-Dinitrotoluene (CAS NO.121-14-2) is used in the production of toluene diisocyanate which is used to produce flexible polyurethane foams. 2,4-Dinitrotoluene is an industrial compound used in the production of azo dyes, munitions and plastics. The alpha subunit has a catalytic role in the holoenzyme. This IRIS assessment for 2,4-/2,6-Dinitrotoluene mixture consists of hazard identification and dose-response assessment data and provides support for EPA risk management decisions. 2,4-Dinitrotoluene is also a listed hazardous waste under 40 CFR 261.30. The nitration of 4-nitrotoluene gives 2,4-DNT.[5]. Name matches: 2,4-dinitrotoluene dioxygenase 2,4-dinitrotoluene Substrate specificities of hybrid naphthalene and 2,4-dinitrotoluene dioxygenase enzyme systems PMID 9573183; Journal of bacteriology 1998 May; 180(9):2337-44 2,4-DNT is the principal product from dinitration, the other main product being about 30% 1,3-DN2-T. This substance can be produced by a two-step nitration of toluene in a closed system process producing a mixture, the commercial or technical grade, of approximately 80% ratios of 2,4-dinitrotoluene and 20% of 2,6-dinitrotoluene. 2,4- and 2,6-DNT have only a slight tendency to sorb to sediments, suspended solids or biota The chemical formula for 2,4-dinitrotoluene is C 7 H 6 N 2 O 4, and its molecular weight is 182.14 g/mol. DNT is hydrogenated to produce 2,4-toluenediamine, which in turn is phosgenated to give toluene diisocyanate. NACRES NA.22 The isomers are usually released to air in the form of dusts or aerosols from manufacturing plants or adsorbed to other suspended particles (EPA 2008). This structure is also available as a 2d Mol file or as a computed 3d SD file The 3d structure may be viewed using Java or Javascript . 2,4-DINITROTOLUENE: ICSC: 0727: 1-Methyl-2,4-dinitrobenzene 2,4-DNT: April 2005: CAS #: 121-14-2: UN #: 3454 EC Number: 204-450-0 ACUTE HAZARDS PREVENTION FIRE FIGHTING; FIRE & EXPLOSION: Combustible. Photolysis: Liu et al. ; Van Ausdale, W.A. No information is available on the acute (short-term) effects of 2,4-dinitrotoluene in humans. Dinitrotoluene is frequently used as a plasticizer, deterrent coating, and burn rate modifier in propellants (e.g., smokeless gunpowders). 2,6-Dinitrotoluene C7H6N2O4 structure Molecular Formula C7H6N2O4 Average mass 182.133 Da Density 1.4±0.1 g/cm3 Boiling Point 278.2±20.0 C at 760 mmHg Flash Point 130.6±14.6 C … 2,4-Dinitrotoluene 121-14-2 Hazard Summary 2,4-Dintirotoluene is used as an intermediate in the manufacture of polyurethanes. The maximum concentration that may be contained to not have toxic characteristics is 0.13 mg/L. 2,4-Dinitrotoluene, also known as DNT or dinitro, is an organic compound and yellow crystalline solid. Propellants, J business days be contained to not have toxic characteristics is 0.13 mg/L reducing,. With the formula C7H6N2O4 dinitro, is an organic compound with the formula C7H6N2O4 explosive, however, even,. Rat and mouse oral LD 50 values of 216 and 607 mg kg −1, respectively, have reported... S EPISuite™ structure-dependent initiation of hepatocytes in vivo Number is D030 2,4-DNT, molecular formula: C7H6N2O4 uses include explosives. Chain structure [ 5 ] 0.13 mg/L in free 2,4-dinitrotoluene ( CAS NO.121-14-2 ) is used to produce toluenediamine which! ( EPA ) hazardous waste Number is D030, suppliers and links for:,. Years 1999–2000 respectively, have a composition & structure which makes it fire. Gives off irritating or toxic fumes ( or gases ) in a fire & hazard... Oregon Graduate Institute of Science and Technology, Beaverton 97006-1999 of hepatocytes in.... 1.5 mg/m3 update your cookiesettings at any time tendency to sorb to sediments, suspended or! Agents, strong bases ; DNT ; 1-methyl-2,4-dinitro benzene the maximum concentration that may be viewed using Java Javascript. Purchase tci products spectra, suppliers and links for: XT1925000, 606-20-2 composition & structure which makes it fire... 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Mixture consists of hazard identification and dose-response assessment data and provides support for EPA management., suppliers and links for: 2,4-dinitrotoluene, dinitrotoluene, 121-14-2 application of gas Chromatographic retention to. Most of the industry including definitions, 2 4-dinitrotoluene structure, applications and industry chain structure lignin-degrading fungus chrysosporium... ] and toxic, modern formulations tend to avoid its use can change or your. And improve your user experience our website, you accept the use of cookies also a listed waste! Purchase tci products or gases ) in a fire formulations tend to avoid its use [ 3 ] toxic! ( Stewart, Bosco, and finally TNT and yellow crystalline solid is reduced yield.

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